Hydrogen is a promising energy carrier, but explosive and difficult to store. But with a new method, households can even produce and store the gas without it becoming dangerous.
On the table are five small vials filled with a viscous liquid ranging from almost transparent to a strong yellowish color. The special thing about this liquid is that it can hold hydrogen. The darker, the more hydrogen atoms it contains. "With the help of a measuring device called a resonator, I can determine the hydrogen content. I do that by measuring the electrical propagation capability in a vibrational field. The resonator tells me what percentage of the carrier medium is loaded with hydrogen," says project manager Nico Weiß, explaining his activity and the idea of using this method to use hydrogen on a larger scale for domestic use. Hydrogen is a gas, therefore requires a lot of volume and can only be stored efficiently with great effort. It is usually stored under high pressure or in liquid form in tanks. The good thing is, by means of wind or solar power, hydrogen can be produced regeneratively and can be used well as a CO2-free fuel for drives. However, due to the potential danger under the Compressed Gas Ordinance, the use of hydrogen to generate heat in homes has so far only been permitted to a limited extent.
Inert like diesel
At Hamburg University of Technology, research is being conducted on an alternative in which households can generate and store hydrogen themselves without it becoming dangerous. Nico Weiß explains why: "The hydrogen atoms are chemically bonded in the process. The main role is played by hydrocarbons, so-called LOHC - Liquid Organic Hydrogene Carriers. This is a synthetic substance that is predominantly produced from petroleum." The idea is that hydrogen atoms can dock onto the organic molecules of LOHCs and be released when needed. White is a research associate at the Institute for High Frequency Technology (IHF). He points to the variously colored vials. "In this storage form, the highly reactive hydrogen becomes tame to the touch and inert, somewhat like diesel oil," says Nico Weiß, describing the process. Via a temperature-controlled reaction, the hydrogen can be separated from the LOHC again and reused in gaseous form.
This process is based on the basic idea of generating a house's energy requirements CO2-free. First, by using a photovoltaic system on the roof to generate electricity, which then uses electrolysis to separate water into its constituent hydrogen and oxygen. For a household, the idea then functions as a heat and energy storage concept. The LOHC is reusable and can probably be charged and discharged up to 1,000 times. "Old petroleum tanks, for example, which can still be found in many basements, serve as storage tanks," says Weiß. Sounds simple and practical. Once the LOHC is old and used up, it can be replaced with the help of a tank truck. "You can think of it like a circular pledge system," explains Weiß, providing a non-hazardous way to store energy. In this way, the regeneratively generated energy can be consumed when it is needed. Even if you come into contact with the oily substance, nothing happens; it is non-toxic.
Increasing efficiency
Currently, one challenge with this concept is determining the hydrogen loading of the LOHC in the process. And this is the task that IHF and Nico Weiß have taken on in the VisPer project. "Because only if you know how much hydrogen is stored in the LOHC can you control the reaction rate and realize efficient storage and release," explains engineer Weiß. Together with the Chair of Process Machinery and Plant Engineering at Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), he is researching the sensor concept based on the interaction of LOHC with electromagnetic waves in the VisPer project funded by the German Research Foundation (DFG). So far, the efficiency is 30 to 40 percent, but LOHCs can store hydrogen for a long time. Disadvantage: Even though the "loaded" LOHC can be stored well, a relatively large amount of it is needed. One kilogram of carrier fluid contains a maximum of 6.2 percent hydrogen.
In the long term, the idea of "refueling" LOHC with hydrogen can also be transferred to other applications. For example, there are offshore wind farms equipped to convert the green electricity produced there directly into hydrogen. "Stored in LOHC, the hydrogen could be transported by ship to a terminal," says Weiß. Again, a sensor will help measure the degree of filling of the LOHC. "We have now reached the next stage with our sensor research. We are still in the planning phase. After that, we'd like to build a prototype of how it could actually be used in a single-family home." And perhaps soon the first households will generate and store their energy in this way.
VisPer is the name of the project in which TU Hamburg is collaborating with Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU) to research a sensor concept for alternative hydrogen storage based on the interaction of hydrocarbons with electromagnetic waves.